Material Safety Data Sheet
Sodium iodate
ACC# 21335
Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium iodate
Catalog Numbers:
AC201760000, AC201761000, AC201765000, AC419560050, AC419565000, NC9048278,
NC9626448, S322-100, S76798
Synonyms:
Iodic acid, sodium salt.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7681-55-2 |
Sodium iodate |
>99 | 231-672-5 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: fine crystalline powder.
Danger! Strong oxidizer. Contact with other
material may cause a fire. Causes eye, skin, and respiratory tract
irritation. Harmful if swallowed.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause eye injury.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. May be harmful if inhaled.
Chronic:
Prolonged or repeated exposure may cause gastrointestinal irritation
and kidney damage. Chronic exposure can lead to iodism characterized
by headache, excess salivation, nasal discharge, conjunctivitis,
laryngitis, bronchitis, stomatitis, enlarged submaxillary glands, and
skin rashes. Chronic ingestion may cause central nervous system
failure.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustion generates toxic fumes. Use water with
caution and in flooding amounts. Oxidizer. Greatly increases the
burning rate of combustible materials. Vapors may be heavier than
air. They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Contact professional fire-fighters immediately.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 1; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Do not use combustible materials such as paper towels to
clean up spill.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with clothing and other
combustible materials. Do not get on skin or in eyes. Avoid
ingestion and inhalation.
Storage:
Do not store near combustible materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from reducing agents.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Sodium iodate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Sodium iodate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystalline powder
Appearance: white - fine
Odor: odorless
pH: Neutral in sol.
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:Decomposes
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:4.28
Molecular Formula:INaO3
Molecular Weight:197.89
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
High temperatures, dust generation, combustible materials, organic
materials.
Incompatibilities with Other Materials:
Strong reducing agents, finely powdered metals, hydrogen peroxide,
sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium
sulfide), combustible materials, flammable liquids.
Hazardous Decomposition Products:
Hydrogen iodide, sodium oxide, iodine.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7681-55-2:
NN1400000
LD50/LC50:
CAS# 7681-55-2:
Oral, mouse: LD50
= 505 mg/kg;
.
Carcinogenicity:
CAS# 7681-55-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
OXIDIZING SOLID, N.O.S. |
OXIDIZING SOLID NOS (SODIUM IODATE) |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN1479 |
UN1479 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7681-55-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7681-55-2: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7681-55-2 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 8 Contact with combustible material may cause fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7681-55-2: 1
Canada - DSL/NDSL
CAS# 7681-55-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 11/16/1998
Revision #4 Date: 2/15/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.